Ionic liquids are compatible with on-water catalysis.
نویسندگان
چکیده
A major limitation of on-water catalysis has been the need for liquid reactants to enable emulsification. We demonstrate that ionic liquids are compatible with on-water catalysis, enabling on-water catalysed reactions for otherwise unreactive solid-solid systems. The unique solvation properties of ionic liquids dramatically expands the scope of on-water catalysis.
منابع مشابه
Homogeneous Catalysis and Catalyst Recovery Using Supercritical Carbon Dioxide and Ionic Liquids
The combination of scCO2 with a non-volatile liquid such as ionic liquids, water, or poly(ethylene glycol) creates a biphasic mixture suitable for homogeneous catalysis with facile catalyst/product separation and catalyst recycling. Continuous-flow processes are also possible. Dissolution of the CO2 into the nonvolatile liquid during the reaction can have desirable or undesirable effects on the...
متن کاملIonic Liquid-Based Microemulsions in Catalysis
The design and properties of surface-active ionic liquids that are able to form stable microemulsions with heptane and water are presented, and their promise as reaction media for thermomorphic palladium-catalyzed cross-coupling reactions is demonstrated.
متن کاملIonic liquids for synthesis of nanoparticles (A review)
An ionic liquid (IL) is a salt in the liquid state. In some contexts, the term has been restricted to salts whose melting point is below some arbitrary temperature, such as 100 °C. While ordinary liquids such as water and gasoline are predominantly made of electrically neutral molecules, ionic liquids are largely made of ions and short-lived ion pairs. These substances are variously called liqu...
متن کاملCofactor-dependent enzyme catalysis in functionalized ionic solvents.
Functionalized, hydrogen-bonding ionic liquids have been successfully evaluated as media for the performance of cofactor-dependent enzyme catalysed oxidations; the effects of incorporating hydroxyl groups into both the cation and anion have been studied and the dependence of activity upon water content has been evaluated.
متن کاملPyridinium based ionic liquids as promoters for a green and selective synthesis of N-monomethylanilines
Pyridinium based ionic liquids derived from β-picoline and n-alkylbromides were synthesized by a simple procedure at ambient temperature and then characterized. These neutral ionic liquids were investigated for their dual role as the solvent and promoter for the selective synthesis of a series of N-monomethylanilines using dimethylcarbonate as the methylating agent. A solvent free gree...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 49 75 شماره
صفحات -
تاریخ انتشار 2013